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A number of our toothpastes do not contain titanium dioxide, including some of our Signal products (Signal Bio, Signal Nature Element, Signal White System, Signal Kids (Baby & Junior), Signal White Now Detox, Signal Anti-Cavity), Love Beauty and Planet and Schmidt’s Naturals.
Moreover, titanium dioxide is recognized for its non-toxic nature and is generally regarded as safe for use in consumer products. This safety profile allows plastic factories to incorporate TiO2 into items that come into contact with food or bodily fluids, such as medical devices, food storage containers, and children's toys, without posing health risks.
The morphology of vitaminB2@P25TiO2NPs is coherent with the description of Degussa P25 typical population. Size distribution histograms were made from manual measures of the nanoparticles observed in SEM micrographs using ImageJ®. This data showed that more than 70% is anatase (between 20 and 60 nm) with a minor amount of rutile characteristic bars (between 80 and 100 nm) and a small amount of amorphous phase (<40 nm) [36]. Further analysis of the same sample areas with an EDS probe demonstrated the presence of organic material composed of C and O (Fig. 2). This material was found homogeneously distributed on the surface of the different shapes of P25TiO2NP, not in the background, indicating a specific interaction that could be attributed to the functionalization of the P25TiO2NPs with vitamin B2.
Lithopone is an inorganic white pigment, obtained from co-precipitation of Zinc sulfide (ZnS) and Barium sulfate (BaSO4). Titanium Dioxide (TiO2) has replaced Lithopone as a white pigment in majority applications as TiO2 is more durable. However, it is much cheaper than TiO2 and has advantages such as low binder requirement and good dispensability. As a white pigment, it can improve the substrate's weather resistance, and improve the fungicidal properties of paint formulations. Some of the major applications of Lithopone include manufacturing of paint pigments, plastic & rubber products, paper, printing inks, cosmetics, and leather & linoleum products. It is commercially available under names such as pigment white 5, Barium zinc sulfate sulfide, Becton White, C.I. 77115, Charlton White, Enamel White, and Zincolith. On the basis of content of ZnS, Lithopone is available at 28%-30% Lithopone and 60% Lithopone.
Due to its light-scattering properties, small amounts of titanium dioxide are added to certain foods to enhance their white color or opacity (1Trusted Source, 3Trusted Source).
Furthermore, the competitive landscape in China's lithopone pigment industry should not be overlooked. Major players like Zhejiang Huayi Chemical, Yunnan Yuntianhua, and Sichuan Long March Chemical compete fiercely, often adjusting their prices to maintain market share.
Various titanium-rich minerals, including ilmenite and rutile, can serve as starting materials for the production of highly purified Titanium Dioxide. The predominant method employed in Titanium Dioxide production is the chloride process. In this process, the mineral, along with coke and chlorine, undergoes a reaction within a fluidized bed, resulting in the formation of primarily titanium tetrachloride and carbon dioxide. Subsequently, the titanium tetrachloride undergoes purification and conversion to Titanium Dioxide. Another method involves treating ilmenite with sulfuric acid to manufacture the chemical.
The manufacturing process of TIO2 pigment involves either the sulfate or chloride process. Each method yields different types of TIO2 particles, which can affect the final product's performance and application. The sulfate process typically produces anatase, a crystalline form of TIO2, while the chloride process yields rutile, another crystalline form known for its superior durability and refractive index.
Rutile, one of the two common natural forms of TiO2, possesses a tetragonal crystal structure that imparts it with superior chemical stability and excellent optical properties. Unlike its anatase counterpart, rutile TiO2 exhibits greater hardness and density, making it more resistant to discoloration and corrosion. This durability makes rutile particularly suitable for outdoor applications where exposure to environmental factors is inevitable.
